Zeroth Law: Thermodynamic Equilibrium
A system in thermodynamic equilibrium is by definition its most probable
state; all processes have essentially gone to completion and its macroscopic
variables are unchanging. Also, if two systems are in thermodynamic
equilibrium with a third they are in thermodynamic equilibrium with each other.
First Law: Conservation of Energy
The increase in energy of a closed system is equal to the energy added in the
form of heat minus the work done by the system on its surroundings:
ΔU = ΔQ - ΔW
Second Law: Entropy Always Increases
The entropy of an isolated system will only increase with time. Generally
ΔS ≥ 0
The entropy will approach a maximum value as the system evolves in time.
Third Law: Absolute Zero
As a system’s temperature approaches absolute zero all processes cease, and
the system entropy approaches its minimum value.
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Zeroth Law
“You must play the game.”
First Law
“You can’t win the game.”
Second Law
“You can’t even lie the game.”
Third Law
“You can’t get out of the game.”
... attributed to C. P. Snow
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